It was Oshoala’s second brace in three days after netting twice in Sunday’s 10-1 win against Real Sociedad, in the maiden Spanish women’s Super Cup.
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Oshoala opened scoring for Barcelona in the 43rd minute before Jenni Hermoso doubled their lead on 48 minutes.
In the 67th minute, Caroline Hansen made it 3-0 while Oshoala added the fourth goal on 71 minutes.
The reigning African Women’s Player of The Year has now scored six goals in her last four games for Barcelona.
The win took Barcelona to the quarter-final of the competition which they have won six times since it began in 1983.
And in Tuesday’s Queens Cup game, Oshoala’s Falcons teammate Uchenna Kanu was in action for Sevilla who beat visiting Levante 3-0.
Kanu was introduced with 10 minutes remaining in the game which was her second outing for Sevilla since joining them.
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