Dedryck Boyata got things off in the 10th minute for the visitors before Dennis Srbeny equalised six minutes into the second half from an extremely tight angle, the assist coming from Ghana forward Christopher Antwi-Adjei’s quick throw-in.
Collins would go on to have a hand in Hertha’s winner after Matheus Cunha’s back heel took a deflection off the Nigeria international on the way into the net.
The 25-year old got booked for a foul in the 73rd minute, but still completed the entire game, making two clearances, three tackles and three interceptions.
Paderborn remain in last place on the Bundesliga log, five points away from safety.
They next face a difficult trip to Bayern Munich next Friday.
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